کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
204203 460705 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Determination of the solubility, dissolution enthalpy and entropy of 3-pentadecylphenyl acrylate in methanol–ethanol solutions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Determination of the solubility, dissolution enthalpy and entropy of 3-pentadecylphenyl acrylate in methanol–ethanol solutions
چکیده انگلیسی

The solubilities of 3-pentadecylphenyl acrylate in methanol–ethanol mixture solvents of different compositions were measured at temperatures ranging from 273.15 K to 297.15 K at atmospheric pressure using a laser detecting system. The solubility data were correlated by the modified Apelblat equation and Buchowski–Ksiazczak λh equation. Both the Apelblat equation and the Buchowski–Ksiazczak λh equation can fit the solubility data well. The dissolution enthalpy and entropy of 3-pentadecylphenyl acrylate were predicted with the solubility data using modified Apelblat equation.


► The solubility of PAPDP in different compositions of methanol–ethanol mixtures solvents was measured.
► The experimental solubility data were correlated by the modified Apelblat equation and Buchowski–Ksiazczak λh equation.
► The dissolution enthalpy and entropy of PAPDP were predicted with the solubility data using modified Apelblat equation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volumes 322–323, 25 May 2012, Pages 26–29
نویسندگان
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