کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
204355 | 460721 | 2007 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Vapour–liquid equilibria, enthalpy of mixing of binary mixtures containing diisopropylether ‘DIPE’ and monoaromatic hydrocarbons: Experimental results and modelling Vapour–liquid equilibria, enthalpy of mixing of binary mixtures containing diisopropylether ‘DIPE’ and monoaromatic hydrocarbons: Experimental results and modelling](/preview/png/204355.png)
The experimental isothermal P–x–y data between 263.15 and 343.15 K at 10 K intervals of liquid binary mixtures 2,2′-oxybis[propane] (diisopropylether or DIPE) + toluene, +m-xylene and of the three pure components are reported. Data reduction by Barker's method provides correlation for excess molar Gibbs energy (GE).Enthalpies of mixing (HE) have been measured for liquid binary mixtures of 2,2′oxybis[propane] (diisopropylether or DIPE) + toluene, +m-xylene at 303.15 K and constant pressure using a C80 calorimeter. A Redlich–Kister type equation [O. Redlichand, A.T. Kister, Ind. Eng. Chem. 40 (1948) 345] was used to correlate experimental values of GE and HE.DISQUAC model [H.V. Kehiaian, Fluid Phase Equilib. 13 (1983) 243; H.V. Kehiaian, Pure Appl. Chem. 57 (1985) 15] has been applied to the binary systems.
Journal: Fluid Phase Equilibria - Volume 255, Issue 1, 1 July 2007, Pages 78–85