کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
204800 460806 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Vapor–liquid–liquid equilibria of perfluorohexane + CO2 + methanol, +toluene, and +acetone at 313 K
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Vapor–liquid–liquid equilibria of perfluorohexane + CO2 + methanol, +toluene, and +acetone at 313 K
چکیده انگلیسی

Homogeneous catalysts offer many advantages over heterogeneous catalysts, such as higher activities and selectivities. However, recovery of homogeneous catalysts is often complicated by difficulties in separating these complexes from the reaction products. The use of gaseous carbon dioxide (CO2) as miscibility switch for organic and fluorous phases has been proposed to overcome this limitation. By using CO2 as a cosolvent, polar organic reactants can be homogenized with catalysts immobilized in a fluorous phase without using elevated temperatures. The phase behavior underlying this concept is investigated.High-pressure phase equilibria for the systems containing carbon dioxide, an organic (methanol, toluene, or acetone), and perfluoro-n-hexane were measured using a variable-volume view cell, by a method capable of rapid and facile measurement of compositions and density in both phases with no sampling or calibration.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fluid Phase Equilibria - Volume 241, Issues 1–2, 15 March 2006, Pages 20–24
نویسندگان
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