کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
205898 | 461127 | 2015 | 7 صفحه PDF | دانلود رایگان |
• Numerous basic species in ethanol-soluble portion from Zhaotong lignite were detected.
• N1Ox class species with 1–12 DBE and 8–34 carbon numbers are dominant in the portion.
• Molecular mass of the detected species in the portion ranges from 100 to 600 u.
• Pyridines and quinolines are the main basic nitrogen species in the portion.
Ethanol-soluble portion (ESP) from Zhaotong lignite ethanolysis at 305 °C was analyzed with a positive-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). The range of molecular mass distribution is from m/z 100 to 600 with the center around m/z 330. Assignment of molecular formulae reveals that the main nitrogen-containing species with relative content of 86.4% are most probably basic nitrogen compounds (BNCs) ionized during ESI in positive-ion mode. The BNCs are N1Ox (x = 0–5) and N2Oy (y = 0–2) with 0–14 double bond equivalent (DBE) values and 9–39 carbon numbers. According to DBE distributions, pyridines and quinolines should be predominant BNCs in the ESP. In addition, amines (DBE < 4) were also identified in the ESP. The average DBE values are 6–8 for N1Ox class species and 7 and 8 for N2Ox class species, indicating that pyridines (or quinolones) and quinolines with an amino group are characteristic structures for N1Ox and N2Ox classes, respectively. Positive-ion ESI FT-ICR MS proved to be a powerful tool for identifying BNCs in coal-derived liquids.
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Journal: Fuel - Volume 141, 1 February 2015, Pages 268–274