Bio-gasoline production from co-cracking of hydroxypropanone and ethanol

Hydroxypropanone was selected as the model compound of bio-oil ketones to study its cracking behavior for bio-gasoline production. The cracking of pure hydroxypropanone generated inferior oil phase which had a content of high oxygenated compounds. The quality of oil phase was obviously improved when ethanol was adopted as the co-reactant. Furthermore, increasing cracking pressure also benefited the yield and quality of the oil phase. The conversion yield of the reactants reached 100% and the selectivity of the oil phase reached 31.9 wt.% in the co-cracking process under 400 °C and 2 MPa. The oil phase also had an outstanding quality with a hydrocarbon content of 100% and mainly contained hydrocarbons with carbon numbers ranging from 7 to 10, which are also important components in commercial gasoline. Based on the results, a co-cracking mechanism was proposed to illustrate the role of ethanol in promoting hydroxypropanone cracking.

► Hydroxypropanone was co-cracked with ethanol for gasoline production.
► Catalyst deactivation was suppressed by co-cracking with ethanol.
► Oil phase was successfully produced with the highest yield of 31.9%.
► Relative content of liquid hydrocarbons in the oil phase reached 100%.