کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
210741 | 461723 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of Ca-substitution in La1 − xCaxFeO3 perovskites on the catalytic activity for soot combustion
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
La1 − xCaxFeO3 (x = 0.1, 0.2, 0.3 and 0.4) perovskites, prepared by the citrate method and characterized by AAS, XRD, TPR-H2 and TPD-O2, were assayed, and its catalytic activity evaluated for soot combustion, using carbon black as a model compound for soot. The catalytic activity was determined by non-isothermal thermogravimetric analysis. A significant enhancement of the catalytic activity was found by increasing the degree of La3+ substitution by Ca2+ in the perovskites, which coincided with an increase of the α-oxygen concentration and thus, a probable enrichment of the CB surface with these oxygenated species, at the start of the combustion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel Processing Technology - Volume 91, Issue 5, May 2010, Pages 546–549
Journal: Fuel Processing Technology - Volume 91, Issue 5, May 2010, Pages 546–549
نویسندگان
R. Jiménez, R. Zamora, G. Pecchi, X. García, A.L. Gordon,