Review on Fischer–Tropsch synthesis in supercritical media

A detailed review of the recent works regarding applications of supercritical media in Fischer–Tropsch synthesis (FTS) is presented. Differences in activity, CH4 and CO2 selectivity, hydrocarbon and olefin distributions, catalyst stability and heat transfer between supercritical Fischer–Tropsch syntheses (SC-FTS) and conventional gas phase Fischer–Tropsch synthesis (GP-FTS) are compared. The effects of temperature, pressure, solvent type, supercritical media/syngas molar ratio on SC-FTS are discussed. Finally selective production of wax via SC-FTS is briefly presented. Experimental analyses reveal that unique properties of supercritical media can improve FTS catalyst activity and selectivity in SC-FTS due to higher heat and mass transfer rates in comparison to GP-FTS.