Effect of structure-directing agent on AlPO4-n synthesis from aluminum dross

The hydrothermal synthesis of AlPO4-n which is a functional material of aluminophosphate, was conducted from two kinds of aluminum dross discharged in an aluminum regeneration factory. The effect of structure-directing agent (SDA) on the formation behavior of AlPO4-n from aluminum dross, the suitable condition to obtain AlPO4-n efficiently, and the pore structure and gas adsorption property were investigated in this study.AlPO4-5 and AlPO4-34 are mainly formed from aluminum dross as a raw material, and it is possible to make AlPO4-5 successfully as a main product by adjusting the amount of triethylamine (TEA) as SDA. The gas adsorption amount with AlPO4-5 is the following order; ammonia > dipropylamine > benzene, and it is found that this order mainly corresponds with the polarity of molecule among them.