کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
214460 | 1425843 | 2008 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Thermal decomposition of copper concentrates under concentrated radiation — Mechanistic aspects of the separation of copper from iron sulfide phases Thermal decomposition of copper concentrates under concentrated radiation — Mechanistic aspects of the separation of copper from iron sulfide phases](/preview/png/214460.png)
The thermal decomposition of two copper concentrates has been studied in an imaging furnace while developing a solar driven process for the extraction of copper. Exposure (heating) of the concentrates in the imaging furnace produced surface temperatures of around 1920 K. Continuous irradiation during 330 s in an argon flow resulted in the removal of 40% of initial sulfur content and the formation of elemental copper. Accelerated sulfur evaporation brought about by repetitive grinding indicates that sulfur elimination is hindered by a slow mass transfer from the interior of the melt to the gas phase. The thermal decomposition of copper concentrates on a technical scale will therefore be most favorably conducted with sub-millimeter particles. Elemental distribution (SEM and EDX) and microprobe analysis revealed that irradiated samples are subject to a temperature gradient. Consequently, elemental copper preferably compacts at the lower surface close to the cold sample support. Exposure of decomposed samples to moderate temperatures around 1400 K showed that tempering of liquid samples will facilitate the separation of metallic copper from residual iron copper sulfides.
Journal: International Journal of Mineral Processing - Volume 88, Issues 1–2, 1 August 2008, Pages 24–30