کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
215304 | 1426236 | 2014 | 6 صفحه PDF | دانلود رایگان |
• Density were reported for HFE-7000 at T from (283 to 363) K and p up to 100 MPa.
• Density were reported for HFE-7100 at T from (283 to 363) K and p up to 100 MPa.
• Modified Tait equations were correlated with the experimental data.
• The isobaric thermal expansivity of HFE-7000 and HFE-7100 were calculated.
• The isothermal compressibility of HFE-7000 and HFE-7100 were calculated.
In this paper, liquid densities for HFE-7000 (1-methoxyheptafluoropropane) and HFE-7100 (methoxy-nonafluorobutane) are reported in the temperature range from (283 to 363) K and pressures up to 100 MPa. The measurements were conducted with a high pressure vibrating-tube densimeter with combined expanded uncertainties (k = 2) of 16 mK in temperature, 0.062 MPa (p < 60 MPa) and 0.192 MPa (60 MPa < p < 100 MPa) in pressure, and 0.6 kg · m−3 in density. The experimental densities were correlated to the modified Tait equation with an absolute average percentage deviation of 0.019% and 0.034% for HFE-7000 and HFE-7100, separately. In addition, the isothermal compressibility and isobaric thermal expansivity have been derived from these density data.
Compressed density data of HFE-7000 (a) and HFE-7100 (b).Figure optionsDownload as PowerPoint slide
Journal: The Journal of Chemical Thermodynamics - Volume 77, October 2014, Pages 131–136