کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
215368 1426235 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Interactions of amino acids with aqueous solutions of hydroxypropyl-β-cyclodextrin at different temperatures: A volumetric and viscometric approach
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Interactions of amino acids with aqueous solutions of hydroxypropyl-β-cyclodextrin at different temperatures: A volumetric and viscometric approach
چکیده انگلیسی


• Densities and viscosities of solutions have been measured at different temperature and p = 100 MPa.
• The relevant parameters of volume and viscosity have been determined for the amino acids.
• The results are used to interpret the (solute + solute) and (solute + solvent) interactions.
• (Host + guest) interactions in these systems are also discussed.

Densities, ρρ, and viscosities, ηη for glycine, l-alanine, l-valine and l-phenyalanine in 0.01 mol · kg−1 aqueous solutions of hydroxypropyl-β-cyclodextrin have been measured at T = (293.15, 298.15, 303.15 and 308.15) K. From these experimental results, the apparent molar volume, VϕVϕ, limiting apparent molar volume, Vϕ0 and the slope, SVSV, transfer volume, ΔVϕ0, limiting apparent molar expansibility, ϕE0, hydration number, nHnH, Falkenhagen coefficient, A, and Jones–Dole coefficient, B, were calculated. The results are interpreted in terms of (solute + solvent) and (solute + solute) interactions in these systems. The trends in transfer volume ΔVϕ0 have been interpreted in terms of (solute + solvent) interactions based on a co-sphere overlap model and (host + guest) interactions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 78, November 2014, Pages 128–133
نویسندگان
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