کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
215718 | 1426260 | 2012 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Supplementary vapor pressure data of the glycol ethers, 1-methoxy-2-propanol, and 2-methoxyethanol at a pressure range of (15 to 177) kPa Supplementary vapor pressure data of the glycol ethers, 1-methoxy-2-propanol, and 2-methoxyethanol at a pressure range of (15 to 177) kPa](/preview/png/215718.png)
The vapor pressure of pure 1-methoxy-2-propanol and 2-methoxyethanol, commonly used as co-solvents in inks, paints, coatings, organic/water solutions among many other applications, were measured with a dynamic recirculation apparatus at a pressure range of (15 to 177) kPa. The measurements were performed at temperature ranges of (342 to 412) K for 1-methoxy-2-propanol and (346 to 417) K for 2-methoxyethanol. The maximum likelihood method was used to estimate the parameters of the Antoine equation, the parameters of an extended Antoine equation and the Wagner equation were determined by non linear least squares method. The three models showed root mean square deviations (rmsd) of 0.39%, 0.38%, and 0.29%, and 0.37%, 0.33%, and 0.32%, for 1-methoxy-2-propanol and 2-methoxyethanol, respectively. Additionally, the experimental data and correlation were compared with those available in the literature.
► Vapor pressure of 2-methoxyethanol and 1-methoxy-2-propanol were measured.
► Complementary data are reported at ranges of (342 to 417) K and (15 to 177) kPa.
► Three commonly used vapor pressure equations were fitted to experimental data.
► The parameters of Antoine and Wagner type equations were estimated.
► The relative deviations (rmsd) from the three vapor pressure equations were <0.4%.
Journal: The Journal of Chemical Thermodynamics - Volume 53, October 2012, Pages 114–118