Measurement of (vapor + liquid) equilibrium for the systems {methanol + dimethyl carbonate} and {methanol + dimethyl carbonate + tetramethylammonium bicarbonate} at p = (34.43, 67.74) kPa

Isobaric (vapor + liquid) equilibrium (VLE) data for the binary system (methanol + dimethyl carbonate) and the ternary system (methanol + dimethyl carbonate + tetramethylammonium bicarbonate) have been measured at p = (34.43, 67.74) kPa using a modified Rose–Williams still. The experimental data for the binary system were well correlated by Wilson, NRTL, and UNIQUAC activity-coefficient models at the two reduced pressures. All the experimental results of the binary system passed the thermodynamic consistency test by the area test of Redlich–Kister and the point test of Van Ness et al. The experimental results of ternary system show that the salt tetramethylammonium bicarbonate has a salting-in effect on methanol. And this effect enhances when the salt concentration increases.

► VLE data for the binary system and the ternary system were measured.
► Methanol, dimethyl carbonate, and tetramethylammonium bicarbonate were studied.
► Isobaric experimental data were measured at p = (34.43, 67.74) kPa.
► VLE data of binary system were correlated with the Wilson, NRTL, and UNIQUAC models.
► The salt effect of TMAB on the VLE of {methanol + DMC} system was investigated.