کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
215781 | 1426256 | 2013 | 9 صفحه PDF | دانلود رایگان |
A systematic thermo-physical characterization of the two compounds 2-((4-acetyl-5-(4-methoxyphenyl)-5-methyl-4,5-dihydro-1,3,4-oxadiazol-2-yl)methylthio)-3-o-tolylquinazolin-4(3H)-one (PDI-A) and 2-((4-acetyl-5-methyl-5-p-tolyl-4,5-dihydro-1,3,4-oxadiazol-2-yl)methylthio)-3-o-tolylquinazolin-4(3H)-one (PDI-G) in two different solvents viz. chloroform (CF) and N,N-dimethylformamide (DMF) were elucidated. Thus, density (ρ), viscosity (η) and ultrasonic sound velocity (U) and thereby various acoustical and thermodynamic parameters have been determined over the range of T = (303, 308, and 313) K and at atmospheric pressure. Moreover, a comparison between experimental results for the pure solvents and solutions of compound PDI-A and compound PDI-G studied has been carried out to analyze carefully how the structural modifications affect the values of Gibbs energy of activation (ΔG), enthalpy of activation (ΔH) and entropy of activation (ΔS) in CF and DMF.
Figure optionsDownload as PowerPoint slideHighlights
► Newly synthesized 1,3,4-oxadiazoles moiety are important heterocyclic compounds.
► Measurement of thermodynamic quantities at three different temperatures.
► Effect of concentration, temperature and nature of solvents in 1,3,4-oxadiazoles.
► Solute–solvent and solute–solute interactions of 1,3,4-oxadiazoles.
Journal: The Journal of Chemical Thermodynamics - Volume 57, February 2013, Pages 436–444