کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
216569 | 1426279 | 2011 | 10 صفحه PDF | دانلود رایگان |
The density, relative permittivity, viscosity and speed of sound at T = (293.15, 298.15, 303.15, 308.15, and 313.15) K in the binary mixtures of nitromethane with 2-methoxyethanol and 2-butoxyethanol have been measured as a function of composition. From the experimental results, the excess molar volumes VE , excess Gibbs free energy of activation for viscous flow (ΔG∗E)(ΔG∗E), excess isentropic compressibility (κsE) and the deviations in the relative permittivity, viscosity, and speed of sound from a mole fraction average have been calculated. The viscosity data, at T = 298.15 K, were correlated with equations of Hind et al., Grunberg and Nissan, Frenkel, and McAllister. The results are discussed in terms of intermolecular interactions and structure of studied binary mixtures.
Journal: The Journal of Chemical Thermodynamics - Volume 43, Issue 3, March 2011, Pages 420–429