کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
216621 | 1426329 | 2007 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Volumetric and refractive properties of binary mixtures containing 1,4-dioxane and chloroalkanes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Volumetric and refractive properties of binary mixtures containing 1,4-dioxane and chloroalkanes Volumetric and refractive properties of binary mixtures containing 1,4-dioxane and chloroalkanes](/preview/png/216621.png)
چکیده انگلیسی
Refractive index deviations, excess volumes, and molar refractions of binary mixtures containing 1,4-dioxane and 1-chloropropane or isomeric chlorobutanes have been calculated from experimental data of refractive indices and densities at temperatures of 298.15 K and 313.15 K. Results obtained have been discussed in terms of intermolecular interactions and a comprehensive discussion has been provided. Excess volumes have been also correlated using Peng–Robinson–Stryjek–Vera cubic equation of state and the relation between parameter b (covolume) from the equation of state and molar refraction has been verified. Refractive indices were compared with those predicted using the equation of state and several mixing rules.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 39, Issue 1, January 2007, Pages 148–157
Journal: The Journal of Chemical Thermodynamics - Volume 39, Issue 1, January 2007, Pages 148–157
نویسندگان
B. Giner, C. Lafuente, A. Villares, M. Haro, M.C. López,