کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
216708 | 1426335 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermodynamics of bis-(η6-diphenyl)chromium (I) fulleride [(η6-Ph2)2Cr]+[C60]− in the range from T → (0 to 360) K
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Thermodynamics of bis-(η6-diphenyl)chromium (I) fulleride [(η6-Ph2)2Cr]+[C60]− in the range from T → (0 to 360) K Thermodynamics of bis-(η6-diphenyl)chromium (I) fulleride [(η6-Ph2)2Cr]+[C60]− in the range from T → (0 to 360) K](/preview/png/216708.png)
چکیده انگلیسی
In the present work, the temperature dependence of heat capacity Cp,m∘=f(T) of crystalline bis-(η6-diphenyl)chromium (I) fulleride [(η6-Ph2)2Cr]+[C60]− has been measured by precision adiabatic vacuum calorimetry between T = (6 and 360) K with an uncertainty of ±0.2%. In this temperature interval, the transformations were detected and their thermodynamic characteristics were estimated. The experimental data were used for calculating standard (po = 0.1 MPa) thermodynamic functions Cp,m∘/R, Δ0THm∘/RT, Δ0TSm∘/R and Φm∘/R=Δ0TSm∘/R-Δ0THm∘/RT (where R is the universal gas constant) in the range T → (0 to 360) K.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 38, Issue 7, July 2006, Pages 810–816
Journal: The Journal of Chemical Thermodynamics - Volume 38, Issue 7, July 2006, Pages 810–816
نویسندگان
N.N. Smirnova, A.V. Markin, T.A. Bykova, I.E. Boronina, G.A. Domrachev, Yu.A. Shevelev, G.V. Markin,