کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
217432 1426328 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Compressed liquid densities of 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Compressed liquid densities of 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa
چکیده انگلیسی

(p, ρ, T) properties were determined in liquid phase for 1-butanol and 2-butanol at temperatures from 313 K to 363 K and pressures up to 25 MPa using a vibrating tube densimeter. The uncertainty is estimated to be lower than ±0.2 kg · m−3 for the experimental densities. Nitrogen and water were used as reference fluids for the calibration of the vibrating tube densimeter. Experimental densities of 1-butanol and 2-butanol were correlated with a short empirical equation and the 11-parameter Benedict–Webb–Rubin–Starling equation of state (BWRS EoS) using a least square optimization. Statistical values to evaluate the different correlations were reported. Published densities of 1-butanol and 2-butanol are compared with values calculated with the BWRS EoS using the parameters obtained in this work. The experimental data determined here are also compared with available correlations for 1-butanol and 2-butanol.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 39, Issue 2, February 2007, Pages 254–260
نویسندگان
, , ,