کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
219529 463278 2011 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A carbon paste electrode impregnated with Cd2+ imprinted polymer as a new and high selective electrochemical sensor for determination of ultra-trace Cd2+ in water samples
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
A carbon paste electrode impregnated with Cd2+ imprinted polymer as a new and high selective electrochemical sensor for determination of ultra-trace Cd2+ in water samples
چکیده انگلیسی

A carbon paste electrode (CP) impregnated with Cd2+ ion imprinted polymer (IIP) was prepared and used for differential pulse voltammetry determination of Cd2+ in real samples. The IIP was prepared by using vinyl pyridine and quinaldic acid as functional monomer and complexing agent, respectively. Voltammetric response of the IIP–CP was considerably higher than that of the electrode modified with the non-imprinted polymer (NIP–CP), indicating properly functioning of the recognition sites of the IIP. Compared to the previously developed cadmium sensors, this sensor showed considerably better resistance against potential interfering agents such as Cu2+, Hg2+ and Pb2+. This sensor showed linear range of 1.0 × 10−9–5.0 × 10−7 M and detection limit of 5.2 × 10−10 M (S/N = 3).


► A new formulation for the preparation of high selective Cd2+ imprinted polymer.
► Cd2+ imprinted polymer as a new electrode modifying agent.
► Ultra-trace cadmium detection limit and higher selectivity compared to the previously reported Cd2+ voltammetric sensors.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 657, Issues 1–2, 1 July 2011, Pages 98–106
نویسندگان
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