کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
219565 463280 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemically fabricated three dimensional nano-porous gold films optimised for surface enhanced Raman scattering
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrochemically fabricated three dimensional nano-porous gold films optimised for surface enhanced Raman scattering
چکیده انگلیسی

The one-step electrochemical fabrication of 3D-nano-porous gold films (NPGFs) was optimised to function as a Surface Enhanced Raman Spectroscopy (SERS) substrate at 785 nm by a central composite experimental design. The concentration of the acid electrolyte (HCl), the potential step time, and the interaction between the acid concentration and the step time all had significant influence on the SERS intensity. The substrate with an optimum SERS intensity of the 1610 cm−1 band from 1,4-benzenedimethanethiol, which was self-assembled on the surface, was fabricated by applying 1.4 V (v Ag|AgCl|3.0 M NaCl) from open circuit potential for 50 s in 2.0 M HCl. The optimised 3D-NPGF substrates have highly uniform coverage of gold nanopores that leads to homogenous SERS intensities across 1000 μm2 of surface. SERS spectra of self-assembled monolayers of organic molecules including 1,4-benzenedimethanethiol, trithiocyanuric acid, 4-mercaptopyridine and 4-mercaptobenzoic acid were obtained using 3D-NPGF substrates.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 656, Issues 1–2, 15 June 2011, Pages 114–119
نویسندگان
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