کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
219757 | 463295 | 2010 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A formal scan rate in staircase and square-wave voltammetry A formal scan rate in staircase and square-wave voltammetry](/preview/png/219757.png)
Because of the fact that real measurements are sometimes described in terms of the (formal) scan rate, the functional relationships between this parameter and the peak current in staircase (SCV) and square-wave voltammetry (SWV) were investigated theoretically. The real SCV peak current is proportional to the square-root of the formal scan rate, v, and inversely proportional to ΔE0.0541: −ip = 0.1453nFScox∗(D/π)½v½ΔE−0.0541. In SWV of a reversible electrode reaction the net peak current depends primarily on the frequency, while the influence of the formal scan rate is of minor importance: Δip = nFScox∗D½(0.7339f½ + 0.0026ΔE0.3118v½). On the other hand, in SWV of a totally irreversible electrode reaction, the real net peak current is a stronger function of the formal scan rate: Δip = 0.0942nFScox∗D½ΔE−0.11v½. Experimental results, obtained in perchlorate solutions of Eu3+, are in relatively good agreement with the theory.
Journal: Journal of Electroanalytical Chemistry - Volume 645, Issue 2, 1 July 2010, Pages 103–108