کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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220020 | 463312 | 2010 | 7 صفحه PDF | دانلود رایگان |
The development of a novel electrochemically stable host–guest supramolecular complex at a host surface is described. It was constructed by combining a self-assembled monolayer (SAM) of mono-(6-deoxy-6-mercapto)-β-cyclodextrin (βCDSH), iron (III) tetra-(N-methyl-4-pyridyl)-porphyrin (FeTMPyP) as the guest-link-molecule and β-cyclodextrin-functionalized gold nanoparticles (βCDAuNP). The building process of the layer-by-layer assembly was monitored by surface plasmon resonance spectroscopy (SPR). The binding processes between the host-functionalized gold surface and the linker molecule (FeTMPyP) were verified to be monovalent, and for host-functionalized gold nanoparticles with FeTMPyP, the interaction was determined to be bivalent. Finally, the electrochemical properties of the electroactive supramolecular multivalent film were determined.
Journal: Journal of Electroanalytical Chemistry - Volume 639, Issues 1–2, 15 February 2010, Pages 36–42