کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
221067 | 463369 | 2007 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Rhodium-modified gold polycrystalline surface as anode material in alkaline medium: An electrochemical and XPS investigation Rhodium-modified gold polycrystalline surface as anode material in alkaline medium: An electrochemical and XPS investigation](/preview/png/221067.png)
A gold polycrystalline electrode modified with rhodium species was characterized by electrochemical and XPS (X-ray photoelectron spectroscopy) techniques in moderately alkaline medium. The Au/Rh electrodes were prepared utilizing a spontaneous deposition process (SDP) of rhodium adlayer on the gold surface. In particular, rhodium deposition was obtained in non-deaerated 50 mM HClO4 solution containing 10 mM RhCl3 at open circuit for a given time. The modified gold electrode with adsorbed rhodium species (Au/Rh) exhibit higher electrochemical activity for the oxygen evolution reaction. The effects on the electrochemical activity of the Au/Rh electrode such as: rhodium coverage, pH, electrolyte composition and applied potentials were critically evaluated and discussed. An optimized pulsed chronoamperometric detection technique for the analytical determination of several mono- and di-protic organic acids such as acetic, tartaric, oxalic, malic, etc., was successfully proposed. An average film composition of Au93±1Rh7±1 was evaluated by XPS technique. The film composition remains unchanged after various electrode treatments such as cycling of potentials and/or polarization conditions for long times in alkaline medium. Thus, the adsorbed rhodium oxide particles show a good chemical and mechanical stability despite the conditions of electrochemical treatment of the electrode surface.
Journal: Journal of Electroanalytical Chemistry - Volume 606, Issue 1, 1 August 2007, Pages 24–32