Enhanced nonlinear optical responses of zinc diaminopyrimidin-2-ylthio phthalocyanine conjugated to AgxAuy alloy nanoparticles

• Diaminopyrimidin-2-ylthio phthalocyaninato zinc (II) is conjugated to Ag-Au nanocomposites.
• The resulting nanocomposites showed enhanced nonlinear optical behaviour when compared to free phthalocyanine.
• Au rich composites enhanced the OL performance of the phthalocyanine more than the Ag rich composite.

In this article, the photophysical and nonlinear optical (NLO) characterizations of diaminopyrimidin-2-ylthio phthalocyaninatozinc (II) (2) before and after conjugation to AgxAuy nano-alloys are discussed. Phthalocyanines-AgxAuy (2-AgxAuy) composites showed enhanced triplet state and nonlinear optical behaviour when compared to free phthalocyanine. Optical limiting (OL) responses of the samples were evaluated using Z-scan technique at 532 nm and 10 ns in dimethyl sulfoxide. Reverse saturable absorption (RSA), which is a direct consequence of triplet absorption of already excited molecules was observed as the dominant mechanism responsible for nonlinearity of the samples. By virtue of the magnitude of absorption coefficients and other NLO optical parameters estimated in this work, 2-AgxAuy composites were found to exhibit stronger optical limiting responses than unconjugated phthalocyanine. The large third-order susceptibilities of the composites make them suitable materials for attenuating modern laser radiations, and also found useful in various optical applications.