Interaction of VOCs with pyrene tetratopic ligands layered on ZnO nanorods under visible light

• First report on combination of ZnO nanorods and pyrene based tetratopic ligands-PTL.
• Enhanced interaction of VOCs with ZnO-PTL under visible light.
• Amines are highly adsorbed by ZnO-PTL when compared to ethanol and hexane.
• COOH in PTL not only helps in anchoring but also adsorbs VOCs preferentially.
• Experimental results are supported by the computational results.

In this work, the relationship between photosensitivity and chemical sensitivity of zinc oxide (ZnO) nanorods coated with pyrene based tetratopic ligands (PTL) is investigated under visible light. The electrical resistance of ZnO-PTL is affected by adsorption of different volatile organic compounds (VOCs) such as ethanol, n-hexane, trimethylamine, and triethylamine. The illumination strongly affects the response to the VOCs. To elucidate the interaction mechanism between PTL and VOCs, the experimental studies have been complemented by first principles calculations. Both experimental and computational results have shown that the amines are bound to PTL with higher affinity followed by ethanol (alcohol) and n-hexane (alkane). Our results have proved that the COOH functional group at the peripheral site of PTL is not only used for anchoring the molecule onto the ZnO, but it is also the main adsorption site for the VOCs, in particular for amines. In practice, the photo-optical properties of pyrene molecules are complemented by the high affinity of COOH group for amines in order to achieve a photo-activated sensor. The complementary use of optical dyes and chemical ligands can provide an innovative methodology for chemical sensors design.

Mechanism of enhanced interaction of volatile organic compounds with hybrid nanomaterials composed of zinc oxide nanorods and pyrene based tetratopic ligands under visible light.Figure optionsDownload as PowerPoint slide