کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
26332 | 43947 | 2012 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Oscillations of the lophyl radical concentration during the photo-decomposition of o-Cl-hexaarylbisimidazole Oscillations of the lophyl radical concentration during the photo-decomposition of o-Cl-hexaarylbisimidazole](/preview/png/26332.png)
Hexaarylbisimidazole (HABI) is a well established photoinitiator in the graphics industry which undergoes in the absence of other reaction partners a fully reversible homolytic bond cleavage into two lophyl radicals L. Surprisingly we now found oscillations of the radical concentration at low temperature in a solution of o-Cl-HABI in toluene, which is an indication of a more complex photochemistry of the HABI/lophyl system. Furthermore this reaction is a very simple example of an oscillating chemical system working under non-flow conditions which involves only one initial reactant. A possible reaction mechanism based on kinetic simulations is proposed.
► Oscillations of the lophyl radical concentration during the photodecomposition of o-Cl-HABI at low temperature in a toluene solution were detected by ESR spectroscopy.
► Kinetic simulations including an autocatalytic step suggest the formation of intermediate radical adducts with solvent molecules, which is an indication of a more complex photochemistry of the HABI/lophyl system.
► This reaction is a very simple example of an oscillating chemical system working under non-flow conditions which involves only one initial reactant.
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 233, 1 April 2012, Pages 60–64