کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
26516 43958 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Disorder/reorientation dynamics of 4-methoxybenzylidene-4-n-butylaniline observed by heterodyne transient grating method
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
Disorder/reorientation dynamics of 4-methoxybenzylidene-4-n-butylaniline observed by heterodyne transient grating method
چکیده انگلیسی


• Photo-induced molecular motion of liquid crystal in an oriented cell was observed.
• Ordered molecules were disordered and recovered depending on the cell direction.
• Molecular response depended on the irradiated light intensity.
• Photo-induced domain formation was proposed for high irradiation intensity.

Molecular dynamics of 4-methoxybenzylidene-4-n-butylaniline (MBBA) in a liquid crystal cell after the perturbation of a UV pulse was observed using the polarization dependent heterodyne transient grating (HD-TG) method. The response of a refractive index change showed different signs depending on the probe polarization, and each response was composed of 4 exponential components. These components were assigned to disordering, 2 types of ordering, and molecular diffusion, judged from the sign of the refractive index change and the dependence on the grating spacing and the pump intensity. The time constants for the disordering and the ordering processes drastically increased for the pump intensity above 0.10 mJ/pulse. To explain the threshold, we proposed that disordering/ordering of domains were observed for the higher pump intensities, while an individual molecule is subject to disordering/ordering for the lower pump intensity.

Pump intensity and probe polarization dependent ordering/reorientation processes of MBBA were observed by a heterodyne transient grating method. We proposed light-induced domains by increasing the pump intensity.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 266, 15 August 2013, Pages 1–5
نویسندگان
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