کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
27091 | 44000 | 2013 | 4 صفحه PDF | دانلود رایگان |
From 2,3-dibromobenz[f]indenone, four compound: 2,3-bis(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenone 1O, 2,3-bis(3,5-dimethyl-4-isoxazolyl)benz[f]indenone 2O, 3-(3,5-dimethyl-4-isoxazolyl)-2-(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenone 3O and 2,3-bis(5-methyl-2-phenyl-4-thiazolyl)benz[f]indenol 4O were prepared, and their photochromic properties were investigated. Among them, photochrome 1O (weak photochromic) and its bisthiazolylbenz[f]indenol derivative 4O displayed photochromism. During ring closure photoreaction, photochrome 4O showed high conversion ratio (98.4%) with low diastereomeric excess (38%).
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► Three new bisarylbenz[f]indenones and one benzindenol were prepared.
► Bisthiazolylbenz[f]indenone 1O and its indenol derivative 4O showed photochromism.
► 4O showed high conversion ratio with moderate diastereoselectivity for ring closure.
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 257, 1 April 2013, Pages 50–53