کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
27208 | 44009 | 2014 | 7 صفحه PDF | دانلود رایگان |
• Three D–π–A organic dyes containing a π-linker of 2,2′-bithiophene unit linked with three electron-donors have been designed.
• The photovoltaic performances of the dyes are characterized and they exhibit relatively high open voltage.
• The structure–performance relationship is primarily studied with the aid of theoretical calculation.
A series of new organic dyes containing 2,2′-bithiophene unit as a π-linker to connect three electron-donors (including carbazole, DH-45; phenothiazine, DH-46; triphenylamine, DH-47) at 3,4′,5′-positions have been designed and synthesized for dye-sensitized solar cells. The experimental results and theoretic calculations indicated that the large steric hindrance among three electron-donors and 2,2′-bithiophene ring partially destroys the whole molecular coplanarity and weakens intramolecular charge transfer (ICT), which results in the narrow, blue-shift of absorption band and decrease of short-circuit current (Jsc). However, the twisted conjugation skeleton for the dyes is favorable for the spatial charge separation that enhances the open-circuit voltage (Voc). Among them, the dye containing carbazole donating group (DH-45) shows best optimized structure for intramolecular charge transfer (ICT) and exhibits better photovoltaic performances than that of the other two dyes (DH-46 and DH-47).
Three new D–π–A conjugated organic sensitizers based on 3,4′,5′-trisubstituted 2,2′-bithiophene were conveniently synthesized. And the photovoltaic performances as well as the structure–property relationship were studied.Figure optionsDownload as PowerPoint slide
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 278, 15 March 2014, Pages 39–45