کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
28475 44076 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The photoinitiated copolymerization of styrenesulfonate with methacrylate monomers in hydrotropic medium
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
The photoinitiated copolymerization of styrenesulfonate with methacrylate monomers in hydrotropic medium
چکیده انگلیسی

Copolymers of styrenesulfonate (StyS) and methyl methacrylate, or hydroxyethyl methacrylate, were prepared by photoinitiated polymerization using the cationic dye Safranine. The reactions were be carried out at StyS concentrations higher than the MHC (0.10–0.15 M) where the monomer forms aggregates. The size of these aggregates depends on the amount of the methacrylic monomer present in the mixture prior to polymerization. The amount of the non-aromatic monomers incorporated in the polymers is mainly determined by the relative reactivity ratios. In the case of HEMA, the lower amount of methacrylate in the aggregates will reduce its proportion in the final polymer. The distribution of the monomers in the copolymers is random, as deduced from the behaviour of the emission spectra, especially the relation between the band corresponding to isolated phenyl rings and that of interacting aromatic systems.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 184, Issue 3, 15 December 2006, Pages 335–339
نویسندگان
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