کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
28575 | 44081 | 2006 | 6 صفحه PDF | دانلود رایگان |

Several bis(biphenyl)ethylenes and ethenes were prepared and their photoisomerization both in solution and in the solid-state was investigated. While all ethylenes and ethenes gave the solutions containing both E- and Z-isomers in the manner of the mutual photoisomerization, the ethylenes having at least one hydrogen atom on the sp2 carbons underwent unidirectional photoisomerization from the Z-isomers to the E-isomers in the solid-state even at low temperature. On the other hand, both the E- and Z-ethenes having no hydrogen atom on the double bonds did not change when irradiated in the solid-state even at room temperature. These different photochemical behaviors can be explained by the Hula-twist (HT) mechanism in such confined environments.
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 184, Issues 1–2, 15 November 2006, Pages 44–49