کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
28622 44082 2006 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Quantum yield enhancement of photoluminescent polycyanate resin by blending with 1-pyrenecarboxylic acid
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
Quantum yield enhancement of photoluminescent polycyanate resin by blending with 1-pyrenecarboxylic acid
چکیده انگلیسی

Polycyclotrimerization of aromatic dicyanate (i.e. bisphenol A dicyanate (BPADCy)) generates photoluminescent (PL) polycyanate (PCn) crosslinked resin with s-triazine ring as the interconnecting point. This inherent s-triazine ring in PCn resin is hydrogen-bond (H-bond) acceptor; therefore, an H-bond donor, 1-pyrenecarboxylic acid (PCA), was used in this study to mix and to co-cure with BPADCy to prepare miscible thin films of PCn/PCA blends through the favorable H-bond interactions. The resulting PCn/PCA blends show their emission patterns characteristic of the PCA and PCn components. An energy transfer process from the PCn matrix to the incorporated PCA is the dominant emission process. Addition of ∼0.7 wt% of PCA in PCn results in the great enhancement on the PL quantum yield from a value of 3.9% for the pure PCn to 54.8% for the corresponding blend.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 180, Issues 1–2, 15 May 2006, Pages 136–142
نویسندگان
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