کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
28683 | 44085 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Use of Cr(phen)33+ as luminescence probe to study the binding constants of phenols to micelles of SDS
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Steady-state and time resolved luminescence quenching measurements of (2T/2E)Cr(phen)33+ were used to investigate the association of phenols to sodium dodecyl sulfate (SDS) micelles. Steady-state results show the quenching process occurs in the micellar pseudo phase. Scatchard plots indicate that the process is a partition between aqueous and micelles. The k+ and kâ rate constant have been evaluated from time resolved data and the binding constants were obtained. The trend found in the K's were 4-H-Ph < 2,6-diMe-Ph < 4-Br-Ph. We concluded that it is possible to use *Cr(phen)33+ as a luminescent probe to determine association parameters for quenchers to micelles of SDS.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 177, Issues 2â3, 25 January 2006, Pages 248-252
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 177, Issues 2â3, 25 January 2006, Pages 248-252
نویسندگان
Daniela Pagliero, Alejandrina Campanella, Gerardo A. Argüello,