کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
29070 | 44118 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Magnetic field effects due to the relaxation mechanism observed for the photo-induced electron transfer reaction of zinc(II) tetraphenylporphyrin and 2-methyl-1,4-naphthoquinone
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Magnetic field effects due to the relaxation mechanism observed for the photo-induced electron transfer reaction of zinc(II) tetraphenylporphyrin and 2-methyl-1,4-naphthoquinone Magnetic field effects due to the relaxation mechanism observed for the photo-induced electron transfer reaction of zinc(II) tetraphenylporphyrin and 2-methyl-1,4-naphthoquinone](/preview/png/29070.png)
چکیده انگلیسی
The magnetic field effects (MFEs) on the photo-induced electron transfer (PET) reaction of zinc(II) tetraphenylporphyrin (ZnTPP) with 2-methyl-1,4-naphthoquinone (2MNQ) in a mixed solvent of cyclohexanol and 2-propanol were investigated at 293 K by a nanosecond laser flash photolysis technique. Upon irradiation of ZnTPP, the electron transfer from ZnTPP to 2MNQ occurred and the corresponding cation and anion radicals were generated. The relative yield of the escaped 2MNQ anion radical, R(B), showed appreciable MFEs. The R(B) values increased between 0 and 0.1 T, then decreased again between 0.1 and 1.65 T. The observed MFEs can be explained in terms of the relaxation mechanism.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 199, Issues 2–3, 25 September 2008, Pages 130–135
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 199, Issues 2–3, 25 September 2008, Pages 130–135
نویسندگان
Masao Gohdo, Yasutaka Kitahama, Yoshio Sakaguchi, Masanobu Wakasa,