Electrocatalytic hydrodehalogenation of atrazine in aqueous solution by Cu@Pd/Ti catalyst

• Uniformly dispersed Pd nanoparticles on Cu sphere cores were obtained.
• The existence of Cu core substantially increased the EASA of Pd.
• The Cu@Pd/Ti cathode exhibited a high activity and stability for the ECH of atrazine.

Electrocatalytic hydrodehalogenation is a cost-effective approach to degrade halogenated organic pollutants in groundwater, and Pd-based catalysts have been found to be an efficient cathode material for this purpose. In this work, a novel Cu@Pd bimetallic catalyst loaded on Ti plate was prepared via combined electrodeposition and galvanic replacement for electrocatalytic hydrodehalogenation of atrazine, a typical halogenated pollutant. The obtained bimetallic catalyst with uniformly dispersed Pd nanoparticles possessed a large electrochemically active surface area of 572 cm2. The Cu@Pd/Ti cathode exhibited a higher electrocatalytic efficiency towards atrazine reduction than the individual Pd/Ti or Cu/Ti cathodes, and achieved up to 91.5% within 120 min under a current density of 1 mA cm−2. Such an electrocatalytic reduction followed pseudo-first-order kinetics with a rate constant of 0.0214 min−1. Atrazine was selectively transformed to dechlorinated atrazine, and its degradation pathway was identified. Current density was found to have a critical influence on the atrazine reduction due to the competitive hydrogen evolution reaction at a higher current density. The fabricated bimetallic catalyst also exhibited a good stability. This work provides an efficient and stable electrocatalyst for chlorinated contaminate removal and groundwater remediation.

Figure optionsDownload as PowerPoint slide