کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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4408750 | 1618858 | 2014 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Electrochemical degradation of nitrobenzene by anodic oxidation on the constructed TiO2-NTs/SnO2-Sb/PbO2 electrode Electrochemical degradation of nitrobenzene by anodic oxidation on the constructed TiO2-NTs/SnO2-Sb/PbO2 electrode](/preview/png/4408750.png)
• Constructed anode was obtained to reveal the mechanism of enhanced performance of PbO2.
• TiO2-NTs/SnO2-Sb/PbO2 anode exhibits high electrocatalytic activity and stability.
• Mass transport is enhanced at the constructed TiO2-NTs/SnO2-Sb/PbO2 electrode.
• The intermediates of nitrobenzene oxidation at PbO2 are confirmed by IC and GC/MS.
The interlayer of Sb-doped SnO2 (SnO2-Sb) and TiO2 nanotubes (TiO2-NTs) on Ti has been introduced into the PbO2 electrode system with the aim to reveal the mechanism of enhanced electrochemical performance of TiO2-NTs/SnO2-Sb/PbO2 electrode. In contrast with the traditional Ti/SnO2-Sb/PbO2 electrode, the constructed PbO2 electrode has a more regular and compact morphology with better oriented crystals of lower size. The TiO2-NTs/SnO2-Sb interlayer prepared by electrodeposition process improves PbO2 coating structure effectively, and enhances the electrochemical performance of PbO2 electrode. Kinetic analyses indicated that the electrochemical oxidation of nitrobenzene on the PbO2 electrodes followed pseudo-first-order reaction, and mass transport was enhanced at the constructed electrode. The accumulation of nitrocompounds of degradation intermediates on constructed electrode was lower, and almost all of the nitro groups were eliminated from aromatic rings after 6 h of electrolysis. Higher combustion efficiency was obtained on the constructed TiO2-NTs/SnO2-Sb/PbO2 electrode. The intermediates of nitrobenzene oxidation were confirmed by IC and GC/MS.
Journal: Chemosphere - Volume 113, October 2014, Pages 48–55