کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4410007 1307522 2012 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pilot scale application of a method for the analysis of perfluorinated compounds in surface soils
موضوعات مرتبط
علوم زیستی و بیوفناوری علوم محیط زیست شیمی زیست محیطی
پیش نمایش صفحه اول مقاله
Pilot scale application of a method for the analysis of perfluorinated compounds in surface soils
چکیده انگلیسی

A growing number of studies now indicate that perfluorinated compounds (PFCs) are globally distributed in the environment. Their widespread distribution and presence in remote locations has led to questions about the importance of atmospheric and oceanic transport. Describing their distribution in surface soils is also an essential but neglected element in developing a comprehensive understanding of their occurrence in the environment. Soils are the critical link between global atmospheric and hydrologic processes where both local and distant contaminants can accumulate and be released into aquatic and terrestrial communities. Because PFC concentrations in soils will influence ground and surface water, wildlife, and crops, methods to accurately measure PFCs in soil are clearly needed. To help answer this need, we developed a method for the analysis of nine perfluorinated carboxylic acids and four perfluorinated sulfonic acids in soil. Samples from six nations (n = 10 per nation) were analyzed by LC-MS/MS to demonstrate the method performance parameters and to make preliminary observations about the occurrence of the PFCs in soils in different parts of the world. The resulting method shows acceptable performance characteristics for the target compounds in most soils while documenting the widespread occurrence of PFCs in surface soils.


► An extraction and LC-MS/MS method were developed for the analysis of PFCs in soil.
► QA/QC parameters are discussed (spike recovery, replicate analysis, QC soil).
► Pilot scale application to 60 unique soils demonstrates method performance.
► Summary statistics for analyzed soils are shown.
► Global scale PFOS and PFOA concentrations are estimated from this study’s data.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemosphere - Volume 86, Issue 3, January 2012, Pages 252–257
نویسندگان
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