Development of the DGT technique for Hg measurement in water: Comparison of three different types of samplers in laboratory assays

The Diffusive Gradients in Thin films (DGT) technique is an operationally defined method to determine the dissolved fraction of trace elements in water. The aim of this study was to develop this technique for the measurement of the bioavailable mercury species in natural waters. For that purpose, three types of DGT units (commercial, manufactured with agarose diffusive gel (DG) and manufactured with polyacrylamide DG) were tested under controlled conditions using an Hg(II) solution both with and without dissolved organic matter (DOM). An acid digestion method using aqua regia was optimised to efficiently digest the resin gel discs prior to analysis. A good performance was obtained for the three DGT types when deployed in a DOM-free mercury solution in the laboratory, and it was demonstrated that polyacrylamide gel can be used as diffusive layer for mercury sampling. However, when the DGT units were deployed in a mercury solution containing DOM, performance differences were observed. Furthermore, the mass of background mercury (blanks) varied among the different DGT types. In the light of the results, the devices manufactured with polyacrylamide DG seemed to be the best choice for dissolved mercury determination.

► We studied the dissolved fraction of Hg in water by using the DGT technique.
► Three different types of DGT units were tested for Hg(II) with and without DOM.
► We demonstrate that polyacrylamide gel do not impede Hg(II) diffusion.
► For first time, diffusion coefficient for Hg(II) in the presence of DOM is shown.
► The DGT unit with polyacrylamide as diffusive gel seems to be the best choice.