کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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4411436 | 1618879 | 2010 | 7 صفحه PDF | دانلود رایگان |
This paper describes analysis of environmental pollutants at depth without bringing sample to the surface. It is based on an improved 3-stage Peltier freeze trap, which efficiently pre-concentrates volatile coal tar and petroleum hydrocarbons, and an integrated system for detecting pollutants on-line, in real-time by photoionization detection and quantitation by gas chromatography/mass spectrometry (GC/MS) as the probe is advanced into the subsurface. Findings indicate measurement precision and accuracy for volatiles meet EPA criteria for hazardous waste site investigations. When a Teflon membrane inlet is used to detect contaminants in groundwater, its 140 °C temperature limit restricts analyte collection in soil to C2-phenanthrenes. Two case studies demonstrate the probe is well-suited to tracking petroleum and coal tar plumes from source to groundwater.
Journal: Chemosphere - Volume 80, Issue 11, September 2010, Pages 1370–1376