Environmental and biological monitoring of volatile organic compounds in the workplace

The exposure of workers to volatile organic compounds (VOCs) in the workplace has been evaluated in four different occupations, namely: house painters, varnishing workers, car painters and petrol station workers. The study was carried out by analyzing the ambient air within the workers’ breathing zone as well as the alveolar air of these workers, which was selected as the biomarker of exposure. Twenty six VOCs were measured in the air samples. Nearly all target VOCs were found in the ambient air of the workplaces assessed, usually involving in the most abundant compounds, toluene, o-xylene and N-butyl acetate, concentrations between 60 and 51 110 μg m−3. The same VOCs were found in the alveolar air of workers after their work shift, at concentrations whose amount depended on the compound and occupation involved. Toluene, at concentrations between 90 and 29 840 μg m−3, o-xylene, between 30 and 12 285 μg m−3, and N-butyl acetate, between 10 and 8045 μg m−3, were also the most abundant compounds found in the alveolar air of workers after exposure. The post-work concentrations of VOCs in alveolar air correlated significantly with ambient air concentrations, obtaining correlation coefficients over 0.9 for the compounds studied. Furthermore, a general trend towards greater absorption of benzene derivatives by the human body (the average percentage of absorption is 50%) than that of esters (average percentage of 20%) has been observed in the data obtained throughout the study.