کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4415645 | 1307754 | 2006 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effects of oxygen, catalyst and PVC on the formation of PCDDs, PCDFs and dioxin-like PCBs in pyrolysis products of automobile residues
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کلمات کلیدی
موضوعات مرتبط
علوم زیستی و بیوفناوری
علوم محیط زیست
شیمی زیست محیطی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effects of oxygen, catalyst and PVC on the formation of PCDDs, PCDFs and dioxin-like PCBs in pyrolysis products of automobile residues Effects of oxygen, catalyst and PVC on the formation of PCDDs, PCDFs and dioxin-like PCBs in pyrolysis products of automobile residues](/preview/png/4415645.png)
چکیده انگلیسی
End-of-life vehicles are dismantled to recover reusable parts and then sent to a shredding facility for steel material recovery. The residue generated from the shredding process, so-called automobile shredder residue, is now being mostly disposed in landfill, however landfill will be prohibited in the near future. More recycling and energy recovery must be made by the regulation. The most appropriate method is the thermal treatment that will produce various forms of fuels and less volume of vitrified residue. In this research, an automobile shredder residue was simulated with considering the residue from a shredding factory based on the new vehicle and thermally treated by pyrolysis or gasification to observe the yields of gas, oil and char. In the temperature range of 400-800 °C, the yields of gas, oil, and char were 38.7-45.8%, 12.3-18.2%, and 36.0-49.0%, respectively. The optimum pyrolyzing temperature for more oil production was around 600 °C. Emission characteristics of the byproducts, PCDDs, PCDFs and dioxin-like PCBs were studied at the temperature of 600 °C. The analysis on the concentration and distribution of the isomers in various forms of the products were completed with and without oxygen, PVC, and catalytic metals, in order to observe how the existence of oxygen, PVC, and catalytic metals affect the formation of PCDDs, PCDFs, and dioxin-like PCBs from pyrolysis or gasification process. Without PVC, no PCDDs, PCDFs and dioxin-like PCBs were found in any products. PCDFs were predominant in any conditions. Catalyst and oxygen were found to affect to form more PCDDs, PCDFs, and dioxin-like PCBs. Effects of catalyst and oxygen on the byproduct formation seemed to be similar in oil and gas while that was different in char.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemosphere - Volume 65, Issue 9, November 2006, Pages 1481-1489
Journal: Chemosphere - Volume 65, Issue 9, November 2006, Pages 1481-1489
نویسندگان
Hyun-Tae Joung, Yong-Chil Seo, Ki-Heon Kim, Yong-Chan Seo,