Fate of nonylphenol polyethoxylates and their metabolites in four Beijing wastewater treatment plants

Four Beijing wastewater treatment plants (WWTPs) were selected to investigate behaviours of nonylphenol polyethoxylates and their metabolites in different wastewater treatment processes. The results showed that the total concentrations of nonylphenolic compounds in the influents of the four WWTPs ranged from 0.115 to 0.347 μmol/L, as well as their removal efficiencies ranging from 75.7% to 90.8%. Both influent concentrations and removal efficiencies of nonylphenol polyethoxylates were correlated to seasons as follows: higher in the summer than in the winter, and influent concentrations were lower during the rain weather. The analysis revealed that 21.8–47.6% of nonylphenol polyethoxylates and their metabolites entering WWTPs were released via effluents and excess sludge, leaving a great part of them for biodegradation. Nonylphenol and short-chain nonylphenol polyethoxylates were disposed to the environment mainly via sewage sludge, while carboxylated nonylphenol polyethoxylates were the most abundant group of nonylphenol polyethoxylates in effluents.