Spatio-temporal occurrences and mineralogical–geochemical characteristics of airborne dusts in Khuzestan Province (southwestern Iran)

Dust storms in Khuzestan province (Iran) are causing problems in industries and human health. To mitigate the impact of those phenomena, it is vital to know the physical and chemical characteristics of airborne dusts. In this paper, we give an overview of the spatio-temporal occurrences and geochemical characteristics of airborne dusts in Khuzestan. Meteorological data from 10 stations in Khuzestan during 1996–2009 indicate (a) an average of 47 dust storm days per year, (b) a lowest annual average of 13 dust storm days in 1998, (c) a highest annual average of 104 dust storm days in 2008, and (d) an average increase of two dust storm days per year. Above-average number of dust storm days usually occurred in the cities of Dezful, Ahvaz, Masjed-e-Soleiman, Abadan and Bostan, whereas below-average number of dust storm days usually occurred in the cities of Mahshahr, Ramhormoz, Behbahan, Shoushtar and Izeh. XRD analyses of airborne dust samples collected in 2008 and 2009 show that the mineralogy of airborne dusts is dominated by calcite, followed by quartz and then kaolinite, with minor gypsum. SEM analyses of the samples indicate that airborne dusts have rounded irregular, prismatic and rhombic shapes. The sizes of airborne dusts vary from 2 to 52 μm, but 10 to 22 μm are the dominant sizes. The smallest and largest dust particles are clays, sulfates or carbonates. XRF and ICP analyses of the samples show that the most important oxide compositions of airborne dusts are SiO2, Al2O3, Fe2O3, CaO and MgO. Estimates of enrichment factors (EF) for all studied elements show that Mn, Hf, U, Sc, K, V and Sr, with EF < 10, are of natural origin, whereas Na, Ni, Co, Ba and Cr, with EF > 10, are of anthropogenic origin. Flat REE patterns with depletion in Th, V, Nb, Zr and enrichment in Al, Rb, Sr and Mn indicate that airborne dusts in Khuzestan come from the same source, which is likely an eroded sedimentary environment outside Iran. In general, airborne dusts in Khuzestan are geochemically similar to airborne dusts elsewhere in the world.

Research Highlights
► We give an overview of the spatio-temporal occurrences and geochemical characteristics of airborne dusts in Khuzestan.
► Meteorological data from 10 stations in Khuzestan during 1996–2009 give information on spatio-temporal occurrence of dust storms.
► Airborne dust samples were collected to obtain TSP, PM2.5 and PM10 by using the high-volume air (HVA) sampler model TCR.
► The mineralogy of airborne dust samples was analyzed by XRD.
► Geochemical characteristics of airborne dusts were studied by XRF and ICP-MS.