کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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4561617 | 1330663 | 2014 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Identification of novel cocoa flavonoids from raw fermented cocoa beans by HPLC–MSn Identification of novel cocoa flavonoids from raw fermented cocoa beans by HPLC–MSn](/preview/png/4561617.png)
• Raw fermented cocoa beans were analysed by LC-MS with fourteen novel flavonoids identified.
Using a detailed HPLC–ESI-MS analysis including both high resolution and tandem MS analysis, a series of fourteen novel flavonoids were identified from alcoholic extracts of raw fermented cocoa beans from Cameroon. The novel compounds include a series of isomeric hexosides of flavan-3-ols and novel proanthocyanidine dimers and trimers and a sulfated flavan-3-ol. Additionally a jasmonic acid sulfate derivative was identified in the cocoa bean extracts as one of the major metabolites produced under fermentation stress. Therefore, the chosen HPLC–ESI-MS analysis method revealed a greater complexity of the cocoa bean polyphenolic extract than previously reported and allowed individual assignment of novel compounds.
Journal: Food Research International - Volume 63, Part C, September 2014, Pages 353–359