کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
45783 | 46422 | 2013 | 5 صفحه PDF | دانلود رایگان |
Photocatalytic conversion of nitrobenzenes in 2-propanol suspensions of bare titanium(IV) oxide (TiO2) under various conditions was examined. Aniline and acetone were simultaneously produced almost stoichiometrically from a 2-propanol suspension of TiO2 containing nitrobenzene under deaerated conditions without the use of a precious metal. Nitrobenzenes having another reducible group such as vinyl, chloro and bromo were chemoselectively reduced to corresponding aminobenzenes in 2-propanol suspensions of a TiO2 photocatalyst with an almost stoichiometric amount of acetone. Photocatalytic reduction of nitrobenzene and oxidation of 2-propanol occurred even in the presence of oxygen, and no re-oxidation of anilines occurred.
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► Photocatalytic reduction of nitrobenzenes in 2-propanol was investigated.
► Bare titanium(IV) oxide was used as photocatalyst.
► Anilines and stoichiometric amount of acetone were simultaneously obtained.
► Nitro group of nitroaromatics having other reducible group was selectively reduced.
► Nitrobenzene was reduced even under air.
Journal: Applied Catalysis B: Environmental - Volumes 134–135, 2 May 2013, Pages 193–197