کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4763164 | 1422964 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Immobilization of aqueous and sediment-sorbed ciprofloxacin by stabilized Fe-Mn binary oxide nanoparticles: Influencing factors and reaction mechanisms
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Fe-Mn binary oxide nanoparticles were reported to be effective for removal of aqueous pharmaceutical chemicals. However, little is known about its potential application in removing the sediment-sorbed contaminants. To bridge this knowledge gap, we synthesized stabilized Fe-Mn binary oxide nanoparticles using water-soluble carboxymethyl celluloses (CMC) as a stabilizer and tested their effectiveness for removal of aqueous and sediment-sorbed ciprofloxacin (CIP). Fully stabilized Fe-Mn binary oxide nanoparticles (0.05Â g/L as Fe) were obtained in the presence of 0.5Â g/L of CMC. When compared with non-stabilized Fe-Mn nanoparticles (FMBO), CMC-stabilized Fe-Mn nanoparticles (CMC-FMBO) showed relatively more favorable removal performance and particles stabilization facilitated delivering nanoparticles into sediment for in situ removal of CIP. The CIP removal by CMC-FMBO was highly pH dependent and the optimum pH was 6.0. A pseudo-second-order kinetic model was able to interpret the removal kinetics. When CIP-spiked sediment was treated with the CMC-FMBO, CMC-FMBO exhibited more excellent resistance to the sediment inhibitive effects and higher removal efficiency of CIP, compared to FMBO. This primary research suggests that CMC-FMBO hold the potential for facilitating removal of emerging contaminants in wastewater and sediment.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 314, 15 April 2017, Pages 612-621
Journal: Chemical Engineering Journal - Volume 314, 15 April 2017, Pages 612-621
نویسندگان
Zhi-li Yan, Yun-guo Liu, Xiao-fei Tan, Shao-bo Liu, Guang-ming Zeng, Lu-hua Jiang, Mei-fang Li, Zan Zhou, Su Liu, Xiao-xi Cai,