کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4764456 | 1423553 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Combustion and flammability chemistry for the refrigerant HFO-1234yf (2,3,3,3-tetrafluroropropene)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Combustion and flammability chemistry for the refrigerant HFO-1234yf (2,3,3,3-tetrafluroropropene) Combustion and flammability chemistry for the refrigerant HFO-1234yf (2,3,3,3-tetrafluroropropene)](/preview/png/4764456.png)
چکیده انگلیسی
A comprehensive chemical mechanism has been developed to describe combustion of the refrigerant HFO-1234yf (2,3,3,3-tetrafluroropropene, YF), revealing the dominant pathways for its stoichiometric combustion with O2. This novel mechanism is a quantum-chemistry-based extension to a previous mechanism developed at NIST for small fluorinated hydrocarbons. The new reactions were proposed by analyzing the YF molecule for potential unimolecular and bimolecular destruction routes, including chemical-activation channels. Kinetic parameters and thermochemistry were calculated using computational quantum chemistry or were developed by analogy to similar reactions or species. The new mechanism was compared favorably to experimental adiabatic-flame-speed data for stoichiometric YF/(35% O2/65% N2) flames at different initial temperatures. Analyses of these predictions revealed the key YF-destruction step at this H-starved condition to be F addition, producing CH2CF2+CF3 via chemically activated (
- CH2CF2CF3)*.
- CH2CF2CF3)*.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Combustion and Flame - Volume 184, October 2017, Pages 176-185
Journal: Combustion and Flame - Volume 184, October 2017, Pages 176-185
نویسندگان
Craig D. Needham, Phillip R. Westmoreland,