کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4766736 | 1424107 | 2017 | 21 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hierarchical (Ni,Co)Se2/Carbon Hollow Rhombic Dodecahedra Derived from Metal-Organic Frameworks for Efficient Water-Splitting Electrocatalysis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, we demonstrate that the electrocatalytic activity of transition metal chalcogenides can be greatly enhanced by simultaneously engineering the active sites, surface area, and conductivity. Using metal-organic frameworks-derived (Ni,Co)Se2/C hollow rhombic dodecahedra (HRD) as a demonstration, we show that the incorporation of Ni into CoSe2 could generates additional active sites, the hierarchical hollow structure promotes the electrolyte diffusion, the in-situ hybridization with C improves the conductivity. As a result, the (Ni,Co)Se2/C HRD exhibit superior performance toward the overall water-splitting electrocatalysis in 1Â M KOH with a cell voltage as low as 1.58Â V at the current density of 10Â mAÂ cmâ2, making the (Ni,Co)Se2/C HRD as a promising alternative to noble metal catalysts for water splitting.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 250, 1 October 2017, Pages 167-173
Journal: Electrochimica Acta - Volume 250, 1 October 2017, Pages 167-173
نویسندگان
Fangwang Ming, Hanfeng Liang, Huanhuan Shi, Gui Mei, Xun Xu, Zhoucheng Wang,