کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4767039 1424116 2017 26 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of pH and Water Structure on the Oxygen Reduction Reaction on platinum electrodes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Effect of pH and Water Structure on the Oxygen Reduction Reaction on platinum electrodes
چکیده انگلیسی
The oxygen reduction reaction (ORR) at different pH values has been studied at platinum single crystal electrodes using the hanging meniscus rotating disk electrode (HMRDE) configuration. The use of NaF/HClO4 mixtures allows investigating the reaction up to pH = 6 in solutions with enough buffering capacity and in the absence of anion specific adsorption. The analysis of the currents shows that the kinetic current density measured at 0.85 V for the Pt(111) electrode follows a volcano curve with the maximum located around pH = 9. This maximum activity for pH = 9 can be related to the effects of the electrode charge and/or water structure in the ORR. On the other hand, the catalytic activity for the other basal planes shows a monotonic behavior with a small dependence of the activity with pH. For stepped surfaces with (111) terraces, the behavior with pH changes gets closer to that of the Pt(111) surface as the terrace length increases. Additionally, the ORR curves show a dependence of the limiting diffusion current with pH. It is observed that the limiting current density diminishes as the pH increases in a potential region where hydrogen peroxide is readily reduced. These results suggest the existence of a bifurcation point in the mechanism previous to peroxide formation, in which OOH
- is proposed as the bifurcation intermediate. The reduction of OOH
- requires proton addition and would be more difficult at neutral pH values, justifying the diminution of the limiting currents.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 241, 1 July 2017, Pages 497-509
نویسندگان
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