کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4767129 1424120 2017 28 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
2D Layered Graphitic Carbon Nitride Sandwiched with Reduced Graphene Oxide as Nanoarchitectured Anode for Highly Stable Lithium-ion Battery
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
2D Layered Graphitic Carbon Nitride Sandwiched with Reduced Graphene Oxide as Nanoarchitectured Anode for Highly Stable Lithium-ion Battery
چکیده انگلیسی
Two dimensional (2D) nanomaterials with high gravimetric capacity and rate capability are a key strategy for the anode of a Li-ion battery, but they still pose a challenge for Li-ion storage due to limited conductivity and an inability to alleviate the volume change upon lithiation and delithiation. In this paper, we report the construction of a 3D architecture anode consisting of exfoliated 2D layered graphitic carbon nitride (g-C3N4) and reduced graphene oxide (rGO) nanosheets (CN-rGO) by hydrothermal synthesis. First, bulk g-C3N4 is converted to nanosheets to increase the edge density of the inert basal planes since the edges act as active Li-storage sites. This unique 3D architecture, which consists of ultrathin g-C3N4 nanosheets sandwiched between conductive rGO networks, exhibits a capacity of 970 mA h g−1 after 300 cycles, which is 15 fold higher than the bulk g-C3N4. The tuning of the intrinsic structural properties of bulk g-C3N4 by this simple bottom-up synthesis has rendered a 3D architectured material (CN-rGO) as an effective negative electrode for high energy storage applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 237, 20 May 2017, Pages 69-77
نویسندگان
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